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The Spectra and Dynamics of Diatomic Molecules , 2nd Ed 796 pages - hardback Academic Press - (isbn 0-12-441456-7) Mar. 2004 |
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| Price: |
97,47 EUR
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| Description: |
This
book is written for graduate students just beginning research, for
theorists curious about what experimentalists actually can and do
measure, and for experimentalists bewildered by theory. It is a guide
for potential users of spectroscopic data, and uses language and
concepts that bridge the frequency-and time-domain spectroscopic
communities. Key topics, concepts, and techniques include: the
assignment of simple spectra, basic experimental techniques, definition
of Born-Oppenheimer and angular momentum basis sets and the associated
spectroscopic energy level patterns (Hund's cases), construction of
effective Hamiltonian matrices to represent both spectra and dynamics,
terms neglected in the Born-Oppenheimer approximation (situations
intermediate between Hund's cases, spectroscopic perturbations),
nonlinear least squares fitting, calculation and interpretation of
coupling terms, semi-classical (WKB) approximation, transition
intensities and interference effects, direct photofragmentation
(dissociation and ionization) and indirect photofragmentation
(predissociation and autoionization) processes, visualization of
intramolecular dynamics, quantum beats and wavepackets, treatment of
decaying quasi-eigenstates using a complex Heff model, and concluding
with some examples of polyatomic molecule dynamics. Students will
discover that there is a fascinating world of cause-and-effect
localized dynamics concealed beyond the reduction of spectra to
archival molecular constants and the exact ab initio computation of
molecular properties. Professional spectroscopists, kinetics, ab initio
theorists will appreciate the practical, simplified-model, and rigorous
theoretical approaches discussed in this book. Key Features: •
A fundamental reference for all spectra of small, gas-phase molecules.
• It is the most up-to-date and comprehensive book on the
electronic spectroscopy and dynamics of diatomic molecules. •
The authors pioneered the development of many of the experimental
methods, concepts, models, and computational schemes described in this
book.
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| Contents List: |
1.
Simple Spectra and Standard Experimental Techniques. 2. Basic Models.
3. Terms Neglected in the Born-Oppenheimer Approximation. 4. Methods of
Deperturbation. 5. Interpretation of the Perturbation Matrix Elements.
6. Transition Intensities and Special Effects. 7. Photodissociation
Dynamics. 8. Photoionization Dynamics. 9. Dynamics.
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| Weight: | 1474 g | |||||||
| Dimensions: | 229 x 152 | |||||||
| Publisher: | Elsevier | |||||||
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